Highly enhanced photoelectric catalysis of WO3 nanoblocks loaded with Ag nanoparticles
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School of Physics, Changchun University of Science and Technology, Changchun 130022, China

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    Abstract:

    WO3/Ag composite film photoanodes were synthesized by hydrothermal combined electrodeposition method. Characterization of samples was conducted by scanning electron microscope (SEM) and X-ray diffraction (XRD), which showed that WO3/Ag composite films had been synthesized. Diffuse reflectance spectra show WO3/Ag composite film has more strong absorption than WO3 film under simulated visible light irradiation. Electrochemical impedance spectroscopy shows WO3/Ag composite film photoanode enhances charge transfer efficiency compared with WO3 film. WO3/Ag composite film photoanodes show higher photocurrent and photoelectric catalytic activity than WO3 film, and the WO3/Ag composite film obtained by depositing Ag nanoparticles at 50 s (WO3/Ag-50) shows the highest photocurrent and photoelectric photoelectric catalytic activity. Meanwhile, the photoelectric catalytic activity of the composite film is higher than their direct photocatalytic and electric catalytic activity. The higher photocurrent and photoelectric catalytic activity of the WO3/Ag composite film photoanodes are attributed to the surface plasmon resonance effect of Ag nanoparticles and Schottky junction effect at the WO3/Ag interface.

    Reference
    [1] HAN S, QU W, XU J, et al. Chemical bath deposition of well-aligned ZnO nanorod arrays on Ag rods for photoelectroncatalytic degradation of rhodamine B[J]. Physical status solidi (a), 2017, 214(9):1700059.1-1700059.7.
    [2] XIE S, OUYANG K. Degradation of refractory organic compounds by photocatalytic fuel cell with solar responsive WO3/FTO photoanode and air-breathing cathode[J]. Journal of colloid and interface science, 2017, 500:220-227.
    [3] SLEIMAN M, CONCHON P, FERRONATO C, et al. Photocatalytic oxidation of toluene at indoor air levels (ppbv):towards a better assessment of conversion, reaction intermediates and mineralization[J]. Applied catalysis B:environmental, 2009, 86(3-4):159-165.
    [4] YANG X, LIU R, HE Y, et al. Enabling practical electrocatalyst-assisted photoelectron-chemical water splitting with earth abundant materials[J]. Nano research, 2015, 8(1):56-81.
    [5] SUN X L, JIA C M, JIA S S, et al. Preparation of all-solid-state Z-type WO3/Ag/Ag3PO4 and study on photodegradation of RhB[J]. Functional materials, 2022, 53(6):119-129.
    [6] LIU C B, TANG F, ZHU C, et al. Preparation and photocatalytic properties of WO3-Ag/graphitic C3N4 Z-scheme composite photocatalyst[J]. Acta materiae compositae sinica, 2021, 38(1):209-220.
    [7] CHENG X F, LENG W H, LIU D P, et al. Enhanced photoelectrocatalytic performance of Zn-doped WO3 photocatalysts for nitrite ions degradation under visible light[J]. Chemosphere, 2007, 68(10):1976-1984.
    [8] YU J, XIONG J, CHENG B, et al. Fabrication and characterization of Ag-TiO2 multiphase nanocomposite thin films with enhanced photocatalytic activity[J]. Applied catalysis B:environmental, 2005, 60(3-4):211-221.
    [9] HARTLAND G V. Optical studies of dynamics in noble metal nanostructures[J]. Chemical reviews, 2011, 111(6):3858-3887.
    [10] HALAS N J, LAL S, CHANG W S, et al. Plasmons in strongly coupled metallic nanostructures[J]. Chemical reviews, 2011, 111(6):3913-3961.
    [11] YAO G Y, LIU Q L, ZHAO Z Y. Applications of localized surface plasmon resonance effect in photocatalysis[J]. Progress in chemistry, 2019, 31(4):516-535.
    [12] ZHANG H, WANG G, CHEN D, et al. Tuning photoelectrochemical performances of Ag-TiO2 nanocomposites via reduction/oxidation of Ag[J]. Chemistry of materials, 2008, 77(1):87-95.
    [13] SUN T H, LIU H J, FU G Y, et al. Measuring and improving response time of WO3 thin film electrochromic
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YANG Jikai, LIU Chunlei, ZHANG Yufei. Highly enhanced photoelectric catalysis of WO3 nanoblocks loaded with Ag nanoparticles[J]. Optoelectronics Letters,2023,19(4):193-199

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History
  • Received:November 01,2022
  • Revised:December 25,2022
  • Online: April 19,2023
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