Archive > Volume 16 Issue 5 > 2020,16(5):360-364. DOI:https://doi.org/10.1007/s11801-020-9178-y CSTR:[cstr] Prev Next
Enhanced mid-infrared emission of non-oxide erbium doped fluorochloride glass
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Abstract:
The fluorochloride glasses samples with good luminescent properties in the infrared region were successfully prepared by melt quenching method. The introduction of Cl- effectively improved the mid-infrared (MIR) luminescence of erbium-doped fluoride glass at 2.7 μm nearby. According to Judd-Ofelt theory, the increase in Ω2 after the introduction of Cl- indicates an increase in the asymmetry and covalence of the sample. X-ray diffraction (XRD), absorption spectrum, Raman spectroscopy, infrared Fourier (FTIR) and infrared fluorescence spectroscopy were specifically conducted. The emission cross section (1.04×10-20 cm2) and the absorption cross section (9.68×10-21 cm2) of the sample at 2.7 μm nearby were calculated by measurement. Therefore, non-oxide erbium-doped fluorochloride glass is a good luminescent material in the MIR band.
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