Preparation and characterization of size controllable spherical silver nanoparticles
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Abstract:
By adjusting pH values of reactant system, the mass ratio of stabilizer/water and aging temperature, size controllable spherical silver nanoparticles (NPs) were synthesized. The properties of silver NPs are characterized by X-ray diffraction (XRD), transmission electron microscope (TEM) and ultraviolet visible (UV-VIS) absorption spectra. Within the pH values of 7.0–11.0, the aging temperature of 80 °C is better to improve silver NPs in shape to nearly sphere, concentrate size distribution and reduce aggregation than the aging temperature of 25 °C. The shape and dispersibility of silver NPs are the best when the pH of the reactant system is within 7.0–8.0. With pH of 7.5, aging at 80 °C, and stabilizer/water mass ratio of 1%, the spherical silver NPs with sizes of 50–70 nm were synthesized. The results are promising to be used to synthesize core/shell NPs when silver NPs are as core.
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This work has been supported by the National Natural Science Foundation of China （Nos.41172110 and 61107090） and Shandong Provincial Natural Science Foundation （No.ZR2011BZ007）.
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