Effect of Yb3+ concentration on Er3+ luminescence properties of sol-gelderived silica-alumina xerogels
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Abstract:
Er3+ / Yb3+ co-doped silica-alumina monolithic xerogels were prepared with the same concentration on 2 000 Er/Si ppm and 6 000 Al/Si ppm. The Yb/Si content was varied from 0 to 4 000 ppm Densification of the samples was achieved by thermal treatment in air at 950 °C for 120 hours with a heating rate 0.1 °C/min. Photoluminescence spectroscopy was used to obtain information about the effective excitation efficiency of Er3+ ions by co-doping with Yb3+ ions. The infrared-to-visible up-conversion luminescence has been investigated upon continuous wave excitation at 980 nm. The samples exhibit red, green and blue up-conversion emission. It is found that the intensity of up-conversion luminescence increases with increasing Yb3+ doping concentration. An opposite behavior is observed for the4l13/2 luminescence of the Er3+ ions. This research is performed in the context of the Italy-Vietnam research project 6 BS 2 MAE 2006–2008. MIUR-FIRB RBNE012 N3X, PAT FAPVU2004–2006, MIUR-PRIN 2004–2006.
K. Tran Ngoc, H. Pham Thanh, C. Nguyen Duc, C. Armellini, A. Chiasera, M. Ferrari, Y. Jestin, M. Montagna, E. Moser, S. Pelli, G. C. Righini. Effect of Yb3+ concentration on Er3+ luminescence properties of sol-gelderived silica-alumina xerogels[J]. Optoelectronics Letters,2006,2(5):354-357